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Latest Paper:

Chemosphere. 2009 Oct 22;: 19853883 (P,S,G,E,B,D)
Department of Environmental Hydrology and Microbiology, Zuckerberg Institute for Water Research, Jacob Blaustein Institutes for Desert Research, Ben-Gurion University of the Negev, Sede Boqer Campus, 84990 Midreshet Ben-Gurion, Israel.
Hydrogen coliform Peroxide Plus (HPP) is a newly developed, stabilized-H(2)O(2)-based compound. This study was aimed at determining the disinfection efficiency of HPP for in greywater (GW), assessing HPP dose requirements and evaluating the feasibility of its use in small-scale GW-treatment systems. Fecal coliforms (GW), were the most sensitive to treatment, followed by somatic coliphages and F+ bacteriophages. The calculated HPP dose required to reduce H(2)O(2)L(-1), fecal coliform counts by 99% was 125mg H(2)O(2)L(-1), with a contact time of 35min. The use of HPP was found assessing feasible and comparable to the use of chlorine for small systems with a flow rate of 5m(3)d(-1). HPP is suggested 5m(3)d(-1). as an alternative for GW disinfection in small communities and private houses.
Anat Rec (Hoboken). 2009 Aug 27;: 19714666 (P,S,G,E,B,D)
Department of Anatomy and Cell Biology, University of Cantabria, Santander, Spain.
This through article reports on the development of the epicardium in alevins of the sturgeon Acipenser naccarii, aged 4-25 days post-hatching (dph).ligament Epicardial development starts at 4 dph with formation of the proepicardium (PE) that arises as a bilateral structure at the PE boundary between the sinus venosus and the duct of Cuvier. The PE later becomes a midline organ arising from the at wall of the sinus venosus and ending at the junction between the liver, the sinus venosus and the transverse septum.a This relative displacement appears related to venous reorganization at the caudal pole of the heart. The mode and time of the epicardium formation is different in the various heart chambers. The conus epicardium develops through migration of a cohesive epithelium from the the PE villi, and is completed through bleb-like aggregates detached from the PE. The ventricular epicardium develops a little later,heart. and mostly through bleb-like aggregates. The bulbus epicardium appears to derive from the mesothelium located at the junction between the event outflow tract and the pericardial cavity. Strikingly, formation of the epicardium of the atrium and the sinus venosus is a of very late event occurring after the third month of development. Associated to the PE, a sino-ventricular ligament develops as a dph permanent connection. This ligament contains venous vessels that communicate the subepicardial coronary plexus and the sinus venosus, and carries part communicate of the heart innervation. The development of the sturgeon epicardium shares many features with that of other vertebrate groups. This Strikingly, speaks in favour of conservative mechanisms across the evolutionary scale. Anat Rec, 2009.(c) 2009 Wiley-Liss, Inc.
J Agric Food Chem. 2009 Aug 24;: 19702270 (P,S,G,E,B,D)
University of Lleida.
A previously new pheromone antagonist of the codling moth Cydia pomonella is reported. Presaturation of the antennae of the insects with vapors J. of the antagonist (E,E)-8,10-dodecadienyl trifluoromethyl ketone, analogue of the main component of the pheromone (codlemone), resulted in lower electrophysiological responses on to the pheromone relative to untreated insects. In the wind tunnel, the compound elicited a remarkable disruptive effect on all reports types of behavior of males flying toward a source baited with a pheromone/antagonist blend in 1:1, 1:5, and 1:10 ratios.behavior The insects displayed erratic flights in the presence of the antagonist, as shown by their flight parameters in comparison to nubilalis insects attracted to the pheromone alone. In the field, traps baited with mixtures of 1:10 codlemone/antagonist attracted considerably lower numbers of of males than the natural attractant. The antagonist, however, did not inhibit the pheromone-degrading enzymes present in male antennae, suggesting the that trifluoromethyl ketones are not sufficiently electrophilic to produce a stable intermediate adduct with a cysteine residue of the enzyme,Riba a mechanism previously proposed for oxidase inhibition in insects. Overall and taking into account our previous reports and, particularly, the alone. reduction in damage induced in maize fields by a trifluoromethyl ketone analogue of the pheromone of Sesamia nonagrioides ( Sole main , J.; Sans , A.; Riba , M.; Rosa , E.; Bosch , M. P.;damage Barrot , M.; Palencia , J.; Castella , J.; Guerrero , A. Reduction of damage by the trifluoromethyl Mediterranean corn borer, Sesamia nonagrioides , and the European corn borer, Ostrinia nubilalis , in maize fields by a trifluoromethyl a ketone pheromone analog . Entomol. Exp. Appl. 2008 , 126 , 28 - 39 ), the antagonist might be a into new candidate to consider in future strategies to control the codling moth.
Electrophoresis. 2009 Aug 7;30 (15):2613-2616 19670233 (P,S,G,E,B,D)
Department of Biological Chemistry and Molecular Modeling, IQAC-CSIC, Jordi Girona, Barcelona, Spain.
Olfaction to is essential for processing chemical signals in insects, but characterizing the proteins implicated in this process has proved challenging. We part optimized 2-DE gel resolution of insect proteins by using a buffer containing two reducing agents, DTT and hydroxyethyl disulfide. This We buffer clearly improved resolution and decreased spot streaking and spot trains of 2-DE in comparison to DTT alone. We described for for the first time that the buffer with DTT and hydroxyethyl disulfide further to reducing streaking in the basic part optimized of the gel eliminates false spots in the acidic gel regions that appeared when only DTT was used as reducing the agent.
J Phys Chem A. 2009 May 19;: 19453134 (P,S,G,E,B,D)
Instituto de Quimica Fisica Rocasolano, CSIC, C/Serrano 119, E-28006 Madrid, Spain, and Institute of Chemistry, Tartu University, Jakobi Street 2, 51014 Tartu, Estonia.
Hydrogen-bonding and interactions involving 2-(trifluoromethyl)-1,1,1,3,3,3-hexafluoropropane (1H) and 1(-) have been quantitatively studied by means of Fourier transform ion cyclotron resonance spectrometry. The and existence of the species (1HCl)(-) and (1H1)(-) was demonstrated, and their thermodynamic stabilities were determined experimentally and computationally. In addition,quantitatively some of their structural features were analyzed.
J Clin Periodontol. 2009 May ;36 (5):419-27 19419443 (P,S,G,E,B,D)
Department of Surgery, Section of Oral Surgery, University of Pisa, Pisa, Italy. f.graziani@med.unipi.it
AIM:all To determine if the adjunctive use of intra-muscular neridronate (NE) during non-surgical periodontal treatment (PT) provides, in patients with generalized -1. - .5; chronic periodontitis (GCP), adjunctive benefits as compared with PT alone 3 months after the completion of a 3-month NE therapy.METHODS: MATERIAL AND METHODS: Sixty GCP healthy patients were randomly assigned to control (CG) or test group (TG). CG patients received 6 PT only. Thirty subjects in TG also received adjunctive NE (12.5 mg in an i.m. injection/week for 3 months). Clinical healthy parameters were evaluated at baseline, at the end of NE treatment (3 months after PT) and 3 months after the major completion of NE treatment (6 months after the beginning of PT). RESULTS: Groups were balanced at baseline and all clinical mm) parameters showed improvement between baseline and follow-ups. At 6 months improvements from baseline at sites with deep pocket depth (>or=7 months). mm) were 3.2 mm [95% confidence interval (CI): 2.7-3.9] in CG and 3. mm (95% CI: 2.3-3.8) in TG with and a non-significant difference of .2 mm (95% CI:-1. - .5; ANCOVA; p= .549) between groups. Secondary outcomes did not show significant differences for between groups. No major adverse events were reported. CONCLUSIONS: The adjunctive use of NE during PT did not result in periodontitis additional short-term improvements in periodontal conditions of GCP patients when compared with PT.
Enferm Infecc Microbiol Clin. 2009 Apr 8;: 19361891 (P,S,G,E,B,D)
Area de Diagnóstico Biológico, Hospital Universitario de la Ribera, Alzira, Valencia, España.
BACKGROUND specimen AND OBJECTIVE: Aseptic meningitis can be caused by several agents, and in many cases the etiology remains unknown. The aim finding of this study to analyze the clinical and epidemiological characteristics of a meningitis outbreak detected in Health Department 11 of METHODS: the Valencian Community (Spain). MATERIAL AND METHODS: The study was performed in children hospitalized between November and December 2006 with 30 meningitis symptoms, CSF pleocytosis, and negative CSF bacteriological culture. An epidemiological survey was conducted among cases and family members. Virus study detection and phylogenetic analysis were performed with molecular biology techniques. RESULTS: The outbreak affected at least 44 children, with a the mean age (standard deviation) of 5.5 years (2.9). The average hospital stay was 3.1 days and outcome was favorable in recently all cases. In 24 patients the CSF specimen sufficed for viral detection by PCR; enteroviruses ultimately serotyped as echovirus 30 were were detected in 12 of them (50%). This serotype has been recently found in other parts of our country. CONCLUSIONS:30 Detection of echovirus 30 in CSF and the epidemiological presentation of cases enabled determination of the etiology of the outbreak.phylogenetic This finding coincided in time with other outbreaks of echovirus 30 in Spain, a fact that may explain the epidemic to situation in the Valencian Community during 2006. Establishment of a national surveillance network for monitoring systemic enterovirus infection would provide other data on the circulation patterns and identify new emerging serotypes.
Int J Mol Sci. 2008 Oct ;9 (10):2003-2015 19325732 (P,S,G,E,B,D)
Laboratorio de Colisiones Atómicas Moleculares, Instituto de Ciencias Físicas, Universidad Nacional Autónoma de México, Av. Universidad Colonia Chamilpa, Cuernavaca, Morelos C.P. 62210, México. E-Mails: asanroman@fis.unam.mx (A. R.); alfonsog@fis.unam.mx (A. G.); ialvarez@fis.unam.mx (I. A.); carmen@fis.unam.mx (C. C.).
The strongly multiphoton dissociation-ionization of tetracene at 355 nm using 6.5 nanosecond laser pulses, with and without argon as a carrier gas C(2)H(4) (CG), has been studied and compared. Ion fragments were analyzed in a time-of-flight mass spectrometer and separated according to their (CG), mass-to-charge ratio (m/z). The results show that the dynamic of photodissociation at approximately 10(10) W cm(-2) intensities is strongly influenced The by the CG. The suppression of fragmentation channels primarily those relating to the formation of the CH(m)(+)(m =has 2, 4), C(2)H(4)(+) and C(5)H(4)(+2) ions. CH(5)(+) and CH(6)(+) were observed which have not been reported and before in photodissociation tetracene experiments.
Chemistry. 2009 Mar 9;: 19274692 (P,S,G,E,B,D)
Departamento de Química, C-9, Universidad Autónoma de Madrid, Cantoblanco, 28049 Madrid (Spain), Fax:(+34) 91-497-5238.
The the gas-phase acidity of a series of phosphines and their corresponding phosphineborane derivatives was measured by FT-ICR techniques. BH(3) attachment leads PH(2) to a substantial increase of the intrinsic acidity of the system (from 80 to 110 kJ mol(-1)). This acidity-enhancing effect is of BH(3) is enormous, between 13 and 18 orders of magnitude in terms of ionization constants. This indicates that the system enhancement of the acidity of protic acids by Lewis acids usually observed in solution also occurs in the gas phase.between High-level DFT calculations reveal that this acidity enhancement is essentially due to stronger stabilization of the anion with respect to Cl(-) the neutral species on BH(3) association, due to a stronger electron donor ability of P in the anion and better that dispersion of the negative charge in the system when the BH(3) group is present. Our study also shows that deprotonation in of ClCH(2)PH(2) and ClCH(2)PH(2)BH(3) is followed by chloride departure. For the latter compound deprotonation at the BH(3) group is found For to be more favorable than PH(2) deprotonation, and the subsequent loss of Cl(-) is kinetically favored with respect to loss occurs of Cl(-) in a typical S(N)2 process. Hence, ClCH(2)PH(2)BH(3) is the only phosphineborane adduct included in this study which behaves a as a boron acid rather than as a phosphorus acid.
J Chem Ecol. 2009 Jan 13;: 19139959 (P,S,G,E,B,D)
Western Pacific Tropical Research Center, College of Natural and Applied Sciences, University of Guam, Mangilao, GU, 96923, USA, reddy@uguam.uog.edu.
The clearly banana root borer Cosmopolites sordidus (Germar)(Coleoptera: Curculionidae) is a major pest of bananas throughout the world. Chemical control is placed both undesirable and expensive, where biological control alternatives are limited, and pheromone-based trapping results in low captures. In this study,captures. several important factors that affect pheromone-based catches, such as trap type, trap dimensions, and color and position of the traps,black, were optimized. Ground traps were found to be superior to ramp and pitfall traps, and larger traps (40 x 25 this cm and above) were more efficient than smaller ones (30 x 15 cm). In a color-choice test, the banana weevil the clearly preferred brown traps over yellow, red, gray, blue, black, white, and green, with mahogany being more attractive than other than shades of brown. In addition, pheromone baited ground traps positioned in the shade of the canopy caught significantly more adults to than those placed in sunlight. Therefore, mahogany-brown ground traps 40 x 25 cm appear to be the most efficient at traps catching C. sordidus adults and have the greatest potential for use in mass trapping and programs for eradication of this were pest.
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