A NbO-type metal-organic framework derived from a polyyne-coupled di-isophthalate linker formed in situ. >> citations
Chenrong Tan,
Sihai Yang,
Neil R Champness,
Xiang Lin,
Alexander J Blake,
William Lewis,
Martin Schröder
School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK.
The polyhedral complex [Cu(4)L(H(2)O)(4)]solv (NOTT-140) shows a 4,8-connected structure of rare scu topology comprising octahedral and cuboctahedral cages; desolvated NOTT-140a shows a total CO(2) uptake of 314.6 cm(3)(STP) cm(-3) at 20 bar, 293 K, and a total H(2) uptake of 6.0 wt% at 20 bar, 77 K.
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